Enzyme
Specific for the penultimate step in salvianin biosynthesis. The enzyme also catalyses the malonylation of shisonin to malonylshisonin [cyanidin 3-O-(6''-O-p-coumaryl-beta-D-glucoside)-5-(6'''-O-malonyl-beta-D-glucoside)]. The compounds 4'''-demalonylsalvianin, salvianin, pelargonidin 3,5-diglucoside and delphinidin 3,5-diglucoside cannot act as substrates.
5MAT
Enzyme
Malonyl-CoA:anthocyanidin 5-O-glucoside-6''-O-malonyltransferase
Enzyme name
EC:2.3.1.172
Entry
Transferases;Acyltransferases;Transferring groups other than aminoacyl groups
Class
malonyl-CoA:pelargonidin-3-O-(6-caffeoyl-beta-D-glucoside)-5-O-beta-D-glucoside 6'''-O-malonyltransferase
Sysname
malonyl-CoA + pelargonidin 3-O-(6-caffeoyl-beta-D-glucoside) 5-O-beta-D-glucoside = CoA + 4'''-demalonylsalvianin [RN:R06799]
Reaction
CoA [CPD:C00010];4'''-demalonylsalvianin [CPD:C12641]
Product
Species information
Manihot esculenta
Species name
Cassava (Manihot esculenta) is a species of eudicot in the family Euphorbiaceae (spurge family).
Species info
Gene sequence info
Manihot_esculenta.5MAT.fa
Download
>rna-XM_021777544.1
MASTDNPVRVVEICPVTPPSDFPESATEFSLPLTFFDTFWFKFHPIERLFFYELTDVTPAFFNSVILPKLKQSLSLALLHFLPIAGKLTWPPHAAKPFIHYAPNDGVSFTIAESDGDFHHLSGRILEAAESYPYVPELPVYDDTAEIISFQITSFPSQGFCIGISSHHAILDGKSVTMFIRAWAHICKQWEKETHPSLLTDLTPIFDRTIIQDPEGLDEVYLNNWFNFFKSIGLDANPRSLKLLPFYGSPPDNLMRGTFEFSREDLNKLRQKILGQLEKVPKEEPDQINPIHLSTFVVSFSYAAVNIVKAKGLERNRKVILGFTADCRARLCPPVPANYFGNCVGISADDDLEAEVIMEENGLAFVAQRLSKLIKKLEKGALEGAKGKLEWALSMPPGSVAVGVAGSPRFKVYEMDFGWGRPKKMEITSIDRRGSISMAESKDGSGGVEIGVALKKHEMDIFDLLFTNGLRDLY
>rna-XM_021777436.1
MASPDSVRVLEVCQVAAASGSPESATALSLPITFLDARYFKFPPAERIYFFKLHGSTPTFFHSVLVPTLKHSLSQTLRHFLPLAGHLTWPPHSPKPIILYSPNDAVSLTIAESDADLDRLVGDEIREASESRLCVPELPISDPKASVIALQITLFLNKGYSISIAMHHAVVDGKTASMFLKAWAHLCKNTAKGQTFTLSPELTPSFDRSTIKDPDELESFYLNHWVATTKLDSKSNPRSLKLLPNLLGVPPKLVRATFQLSRENIEKLRGAVVSYHQHGAAGLQPTREVRLSTFVLTCAYLSVCLVKARGGDANRMVYFLVAADCRSRLDPPISQNYFGNGVFVHDTVIEARTFMEENGVAIIAEKISGIIKGLEKGLFRGAKESHERLRSTGADVQKIGIAGSPRFLYYEEDFGWGKPNKVEIASIDRINGVSLMESRDGNGGIEIGIVMQRHEMEAFASLFVQGLN
>rna-XM_021777428.1
MASINNPVRLVEICPVTPSSDSPESATELSLPLTFFDAFWFKFHPVERIFFYELTDSTPAFFNSVILPKLKQSLSLALLHFLPLAGKLTWPPHAAKPFIHYVPNDAVSLTIAESDGDFHHLSGRILEAAESYPYVPELPVYDDTAEIISFQITSFPSQGFCIGISSHHAILDGKSVTMFIRAWAHICKQWEKETHPSLLTDLTPIFDRTIIQDPEGVDEVYLNNWFNFFKSIGLDANPRSLKLLPFYGSTPDNLMRGTFEFSRDDLKKLRQKILSQLEKVPKEEPDQITPIHLSTFVLSYSYAVVSLVKAKGIERNRKMIFGFTADCRARLDPPVPANYFGNCVGISADDLEAEVIMEENGLAFVAQRLSKLIKKLEKGALEGAKGKLEWALSIPPGSVAAGVAGSPRFKVYEMDFGWGRPKKVEITSIDRTGSISMAESKDGSGGIEIGVALKNNEMEIFDLLFTNGLRDL
>rna-XM_021777421.1
MASPDSVRVLEVCQVAAASGSPESATALSLPITFLDARYFKFPPAERIYFFKLHGSTPTFFHSVLVPTLKHSLSQTLRHFLPLAGHLTWPPHSPKPIILYSPNDAVSLTIAESDADLDRLVGDEIREASESCLCVPELPISDTKASVIALQITLFLNKGYSISIAMHHAVVDGKTASMFLKAWAHLCKNTSKGQTFTLSPELTPSFDRSTIKDPDELESFYLNHWVATTKLDSKSNPRSLKLLPNLLGVPPKLVRATFQLSRENIEKLREAVVSYHQHGAAGLQPTREVRLSTFVLTCAFLSVCLVKARGGDANRMVYFLVAADCRSRLDPPISQNYFGNGVFVHDTVIEARTFMEENGVAIIAEKISGIIKGLEKGLFRGAKESHERLRSTGADVQKIGIAGSPRFLYYEEDFGWGKPNKVEIASIDRIHGVSLMESRDGNGGFCFPVCSRPELTGCWFLNHLSSVVFSTVRIIYNQACSFFGYRVLI
>rna-XM_021745835.1
MASINNQVRVLEICQVTSFSDSPDSATELSLPLTFFDTFWFKFPPTERIFFYQLTDATPAFFHSVILPKLKQSLSLTLLHFLPLAGKLTWPPHAAKPFILYAPNNAIPISIAESDADFHHLSDTIHEADESHPYIPELPVSDSCADIISLQITLFPNQGFCIGISSHHAILDGKSVTMFIRAWAHICKHSQNEKNPTLLPELTPIFDRTMIQDPEGLDMVYLNNWLSIFKSIGFDGNPRTLKLLPAFNGLPANLVRGTFELSREALKKLRQKVLSQLERVDPEQTKTIHLSTFVLTLAYAVVSIVKAKGLERNTKVVFAFTADCRARLEPPLPANYFGNCVSGYNDATEAEVLMEENGIAFVVQRLSKLIKGLEKGALEGAKNKLESFMEKKPDSLEVIGVAGSPRFQVYESDFGWGRPKMVEVTSIDRTGSISMAESKDESGGVEIGIVLKQHEMEKFDSLFINGLKE
>rna-XM_021770888.1
MASPCSTKILDFCQVLPAYDSPESATEFSLPLTFFDMLWLKLPPVQRLFFYQLTDPSATPAFFNTVILPKLKHSLSLTLVHFLPLAGHLTWPPNLPKPFILYTPNDGVPFTVADSDADFDRLSSDNILNAVELHPYVPELPISDTMASLLALQITLFPNKGFSIGYSINHALLDGKSIIMFMKYWAHISKHGENGKQNSSMLLEELAPFYDRSGIEDPLELGNLYLSQWESLAESEPMSNPRSLKLLPQLGADIKRVRSTFHLTREEINKLKNKVLSQLENPIPLSTFVVTCAYVLVCMVKARGGDGSRMVWFTFAVDCRRRLDPPLPANYFGNCVAVHDVSTEARDIMEGNGFSSIAKRLSGVIEGLKKGLFQRAADMAPRLKNAIITGAQVIGLAGSTRFDVYECDFGWGRPKKVEIISIDKTGAISLTQSRDGNGGIQIGLALSKDEMEAFASLFVDGLKHLQ
>rna-XM_021769887.1
MALPCSTKILEFCQVLPAYDSPESATEFSLPLTFFDIFWLKLSPVQRLFFYQLTGPSATPTFFNTVILPKLKHSLSLTLFHFLPLVGRLTWPPNCPKPFILYTPNDGVPLTVAESDADFDRLSSDDILDAVELHPYVPDLPVSDTMASILALEITLFPNKGFSIGYSINHAVLDGKSITMFMKSWAYMSKHGENGKQNTSILPEELAPFFDRNGIKDPLELGNLFLRQWESLSESEPMINSRSLKLLPQLGADIKKVRSTFHLTREEIIKLKNKVLSQLENPIPLSTFVVTCAYVLVCMVKAKGGDGNRMVWFLFAVDCRRRLDPPLPANYFGNCVAGHDVFTEARDFMEENGFSNIAKRLSGVIEGLEKDPLQGAEDKISSFKSEIRAGMQVIGLAGSTTFDVYGCDFGWGRPKKVEITSIDKTGAISLTQSRDGNRGIQIGLVLSRDEMEAFGSLFVDGLKHL
MASTDNPVRVVEICPVTPPSDFPESATEFSLPLTFFDTFWFKFHPIERLFFYELTDVTPAFFNSVILPKLKQSLSLALLHFLPIAGKLTWPPHAAKPFIHYAPNDGVSFTIAESDGDFHHLSGRILEAAESYPYVPELPVYDDTAEIISFQITSFPSQGFCIGISSHHAILDGKSVTMFIRAWAHICKQWEKETHPSLLTDLTPIFDRTIIQDPEGLDEVYLNNWFNFFKSIGLDANPRSLKLLPFYGSPPDNLMRGTFEFSREDLNKLRQKILGQLEKVPKEEPDQINPIHLSTFVVSFSYAAVNIVKAKGLERNRKVILGFTADCRARLCPPVPANYFGNCVGISADDDLEAEVIMEENGLAFVAQRLSKLIKKLEKGALEGAKGKLEWALSMPPGSVAVGVAGSPRFKVYEMDFGWGRPKKMEITSIDRRGSISMAESKDGSGGVEIGVALKKHEMDIFDLLFTNGLRDLY
>rna-XM_021777436.1
MASPDSVRVLEVCQVAAASGSPESATALSLPITFLDARYFKFPPAERIYFFKLHGSTPTFFHSVLVPTLKHSLSQTLRHFLPLAGHLTWPPHSPKPIILYSPNDAVSLTIAESDADLDRLVGDEIREASESRLCVPELPISDPKASVIALQITLFLNKGYSISIAMHHAVVDGKTASMFLKAWAHLCKNTAKGQTFTLSPELTPSFDRSTIKDPDELESFYLNHWVATTKLDSKSNPRSLKLLPNLLGVPPKLVRATFQLSRENIEKLRGAVVSYHQHGAAGLQPTREVRLSTFVLTCAYLSVCLVKARGGDANRMVYFLVAADCRSRLDPPISQNYFGNGVFVHDTVIEARTFMEENGVAIIAEKISGIIKGLEKGLFRGAKESHERLRSTGADVQKIGIAGSPRFLYYEEDFGWGKPNKVEIASIDRINGVSLMESRDGNGGIEIGIVMQRHEMEAFASLFVQGLN
>rna-XM_021777428.1
MASINNPVRLVEICPVTPSSDSPESATELSLPLTFFDAFWFKFHPVERIFFYELTDSTPAFFNSVILPKLKQSLSLALLHFLPLAGKLTWPPHAAKPFIHYVPNDAVSLTIAESDGDFHHLSGRILEAAESYPYVPELPVYDDTAEIISFQITSFPSQGFCIGISSHHAILDGKSVTMFIRAWAHICKQWEKETHPSLLTDLTPIFDRTIIQDPEGVDEVYLNNWFNFFKSIGLDANPRSLKLLPFYGSTPDNLMRGTFEFSRDDLKKLRQKILSQLEKVPKEEPDQITPIHLSTFVLSYSYAVVSLVKAKGIERNRKMIFGFTADCRARLDPPVPANYFGNCVGISADDLEAEVIMEENGLAFVAQRLSKLIKKLEKGALEGAKGKLEWALSIPPGSVAAGVAGSPRFKVYEMDFGWGRPKKVEITSIDRTGSISMAESKDGSGGIEIGVALKNNEMEIFDLLFTNGLRDL
>rna-XM_021777421.1
MASPDSVRVLEVCQVAAASGSPESATALSLPITFLDARYFKFPPAERIYFFKLHGSTPTFFHSVLVPTLKHSLSQTLRHFLPLAGHLTWPPHSPKPIILYSPNDAVSLTIAESDADLDRLVGDEIREASESCLCVPELPISDTKASVIALQITLFLNKGYSISIAMHHAVVDGKTASMFLKAWAHLCKNTSKGQTFTLSPELTPSFDRSTIKDPDELESFYLNHWVATTKLDSKSNPRSLKLLPNLLGVPPKLVRATFQLSRENIEKLREAVVSYHQHGAAGLQPTREVRLSTFVLTCAFLSVCLVKARGGDANRMVYFLVAADCRSRLDPPISQNYFGNGVFVHDTVIEARTFMEENGVAIIAEKISGIIKGLEKGLFRGAKESHERLRSTGADVQKIGIAGSPRFLYYEEDFGWGKPNKVEIASIDRIHGVSLMESRDGNGGFCFPVCSRPELTGCWFLNHLSSVVFSTVRIIYNQACSFFGYRVLI
>rna-XM_021745835.1
MASINNQVRVLEICQVTSFSDSPDSATELSLPLTFFDTFWFKFPPTERIFFYQLTDATPAFFHSVILPKLKQSLSLTLLHFLPLAGKLTWPPHAAKPFILYAPNNAIPISIAESDADFHHLSDTIHEADESHPYIPELPVSDSCADIISLQITLFPNQGFCIGISSHHAILDGKSVTMFIRAWAHICKHSQNEKNPTLLPELTPIFDRTMIQDPEGLDMVYLNNWLSIFKSIGFDGNPRTLKLLPAFNGLPANLVRGTFELSREALKKLRQKVLSQLERVDPEQTKTIHLSTFVLTLAYAVVSIVKAKGLERNTKVVFAFTADCRARLEPPLPANYFGNCVSGYNDATEAEVLMEENGIAFVVQRLSKLIKGLEKGALEGAKNKLESFMEKKPDSLEVIGVAGSPRFQVYESDFGWGRPKMVEVTSIDRTGSISMAESKDESGGVEIGIVLKQHEMEKFDSLFINGLKE
>rna-XM_021770888.1
MASPCSTKILDFCQVLPAYDSPESATEFSLPLTFFDMLWLKLPPVQRLFFYQLTDPSATPAFFNTVILPKLKHSLSLTLVHFLPLAGHLTWPPNLPKPFILYTPNDGVPFTVADSDADFDRLSSDNILNAVELHPYVPELPISDTMASLLALQITLFPNKGFSIGYSINHALLDGKSIIMFMKYWAHISKHGENGKQNSSMLLEELAPFYDRSGIEDPLELGNLYLSQWESLAESEPMSNPRSLKLLPQLGADIKRVRSTFHLTREEINKLKNKVLSQLENPIPLSTFVVTCAYVLVCMVKARGGDGSRMVWFTFAVDCRRRLDPPLPANYFGNCVAVHDVSTEARDIMEGNGFSSIAKRLSGVIEGLKKGLFQRAADMAPRLKNAIITGAQVIGLAGSTRFDVYECDFGWGRPKKVEIISIDKTGAISLTQSRDGNGGIQIGLALSKDEMEAFASLFVDGLKHLQ
>rna-XM_021769887.1
MALPCSTKILEFCQVLPAYDSPESATEFSLPLTFFDIFWLKLSPVQRLFFYQLTGPSATPTFFNTVILPKLKHSLSLTLFHFLPLVGRLTWPPNCPKPFILYTPNDGVPLTVAESDADFDRLSSDDILDAVELHPYVPDLPVSDTMASILALEITLFPNKGFSIGYSINHAVLDGKSITMFMKSWAYMSKHGENGKQNTSILPEELAPFFDRNGIKDPLELGNLFLRQWESLSESEPMINSRSLKLLPQLGADIKKVRSTFHLTREEIIKLKNKVLSQLENPIPLSTFVVTCAYVLVCMVKAKGGDGNRMVWFLFAVDCRRRLDPPLPANYFGNCVAGHDVFTEARDFMEENGFSNIAKRLSGVIEGLEKDPLQGAEDKISSFKSEIRAGMQVIGLAGSTTFDVYGCDFGWGRPKKVEITSIDKTGAISLTQSRDGNRGIQIGLVLSRDEMEAFGSLFVDGLKHL
Gene tree
Gene tree
Sheng jun & Dong yang Teams, Yunnan agriculture University